Synthesis of poly-2-hydroxyethyl methacrylate–montmorillonite nanocomposite via in situ atom transfer radical polymerization
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چکیده
منابع مشابه
poly(styrene-co-butyl acrylate)/clay nanocomposite latexes synthesized via in situ atom transfer radical polymerization in miniemulsion: activators generated by electron transfer approach
w ater born poly(styrene-butyl acrylate)/clay nanocomposite latexes were synthesized by a novel initiating system of activators generated by electron transfer (aget) in a system of atom transfer radical polymerization (atrp). initially, the clay was swelled in a mixture of styrene, butyl acrylate, and hexadecane. the mixture was then sonicated to obtain a stable miniemulsion. to s...
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atom transfer radical polymerization of styrene (st) and methyl methacrylate (mma) was performed at 90oc in the absence and presence of nanoclay (cloisite 30b). trichloromethyl-terminated poly(vinyl acetate) telomerand cucl/ pmdeta were used as a macroinitiator and catalyst system, respectively. the experimental results showed that the atom transfer radical polymerization of st and mma in the a...
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styrene nanocomposites were synthesized by in-situ atom transfer radical polymerization at 110oc. the variations of monomer conversion and the linearity of semilogarithmic kinetic plot, some signs of living polymerizationand constant radical concentration in the reaction medium, were revealed by gas chromatography technique (gc). according to the gel permeation chromatography (gpc) results, the...
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In current study,a hydrogel based on biocompatible polymerwas prepared. The functionalization of polyvinyl alcohol (PVA)with epichlorohydrin(ECH) to produce epichlorohydrin-g-polyvinyl alcohol (PVA/ECH) as a suitable macroinitiator for atom transfer radical polymerization (ATRP) reaction was investigated.ThenN-vinyl pyrrolidone (NVP) waspolymerized on the surface of macroinitiatorin presence of...
متن کاملMathematical Modeling of Atom Transfer Radical Polymerization
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ژورنال
عنوان ژورنال: Journal of Materials Research
سال: 2008
ISSN: 0884-2914,2044-5326
DOI: 10.1557/jmr.2008.0396